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Magnetic Functions Beyond the Spin-Hamiltonian (Structure and Bonding) (Structure and Bonding) [Hardcover]

By R. Boca
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Item description for Magnetic Functions Beyond the Spin-Hamiltonian (Structure and Bonding) (Structure and Bonding) by R. Boca...

Using the spin-Hamiltonian formalism the magnetic parameters are introduced through the components of the Lambda-tensor involving only the matrix elements of the angular momentum operator. The energy levels for a variety of spins are generated and the modeling of the magnetization, the magnetic susceptibility and the heat capacity is done. Theoretical formulae necessary in performing the energy level calculations for a multi-term system are prepared with the help of the irreducible tensor operator approach. The goal of the programming lies in the fact that the entire relevant matrix elements (electron repulsion, crystal field, spin-orbit interaction, orbital-Zeeman, and spin-Zeeman operators) are evaluated in the basis set of free-atom terms. The modeling of the zero-field splitting is done at three levels of sophistication. The spin-Hamiltonian formalism offers simple formulae for the magnetic parameters by evaluating the matrix elements of the angular momentum operator in the basis set of the crystal-field terms. The magnetic functions for dn complexes are modeled for a wide range of the crystal-field strengths.

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Item Specifications...

Pages   276
Est. Packaging Dimensions:   Length: 9.4" Width: 6.3" Height: 0.7"
Weight:   1.3 lbs.
Binding  Hardcover
Release Date   Feb 1, 2006
Publisher   Springer
ISBN  354026079X  
ISBN13  9783540260790  

Availability  79 units.
Availability accurate as of Oct 22, 2016 02:21.
Usually ships within one to two business days from La Vergne, TN.
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